Boot it with the minimum components:
- PSU
- Motherboard
- CPU + heatsink
- 1 stick of ram
- Video card (If there is no integrated graphics)
If it doesn't POST, take out the stick of ram, and try with another stick.
You can also test it without the video card - if there is a motherboard
speaker. It will beep if it POSTs - so you won't have to check visually
on the monitor if it did.